CFC use, harmful effects and ozone layer depletion explained
Uses of CFC and Decay of the Ozone Layer
Question: What is CFC? Write down its characteristics.
Answer: CFCs are fluorine and chlorine derivatives of methane and ethane. The commercial name for CFC gases is Freon. Among them, Freon-11 (CCl₃F), Freon-12 (CCl₂F₂), and Freon-114 (CClF₂–CClF₂) are notable. Additionally, CHClF₂ (HCFC-22), Halon-1211 (CF₂BrCl), and Halon-1301 (CF₃Br) are also well-known compounds.
Characteristics: CFCs have low melting and boiling points; they are odorless, non-flammable, inert, insoluble in water, and non-toxic. The most significant advantage of CFCs is that their boiling points are near room temperature, allowing them to be liquefied under slight pressure for various uses. For example, the boiling points of CFC-11 (CCl₃F) and CFC-12 (CCl₂F₂) are 23.8°C and -29.8°C (revised), respectively.
Characteristics: CFCs have low melting and boiling points; they are odorless, non-flammable, inert, insoluble in water, and non-toxic. The most significant advantage of CFCs is that their boiling points are near room temperature, allowing them to be liquefied under slight pressure for various uses. For example, the boiling points of CFC-11 (CCl₃F) and CFC-12 (CCl₂F₂) are 23.8°C and -29.8°C (revised), respectively.
Question: Write the principle of production for CFC-12 and CFC-11.
Answer: CFC-12 is produced by reacting a mixture of CCl₄ and HF in the presence of SbCl₅.
Combined production of CFC-11 and CFC-12: Heating CCl₄ and HF in the presence of (C + FeCl₂) at 300°C produces both CFC-11 and CFC-12.
CCl₄ + 2HF → CCl₂F₂ + 2HCl
Combined production of CFC-11 and CFC-12: Heating CCl₄ and HF in the presence of (C + FeCl₂) at 300°C produces both CFC-11 and CFC-12.
2CCl₄ + 3HF → CCl₂F₂ + CCl₃F + 3HCl
Question: Write the uses of CFC.
Answer:
- CFCs are used as solvents in producing toxic solutions for insecticides and pest control.
- CFCs are used in inhalers for respiratory treatment and in various medical sprays.
- CFCs are used for cleaning surgical instruments.
- Due to their low boiling points, CFCs are used in various refrigeration and air conditioning systems.
- CFC compounds are also used in fire extinguishers.
Question: What is called the Ozone Layer?
Answer: The layer of air containing ozone gas, located at an altitude of 15-30 km (or 20-50 km according to some sources) within the stratosphere or calm layer, is called the ozone sphere or ozone layer.
Question: What is an Ozone Hole?
Answer: The depletion of the ozone layer located in the stratosphere, at an altitude of 20-30 km from the Earth’s surface, creates a hole known as an “ozone hole.” Scientist Farman identified the depletion of the ozone layer as an ozone hole.
Question: Explain the mechanism of ozone layer depletion.
Answer: Due to being highly stable, CFCs released from various sources reach the stratosphere of the atmosphere unchanged. This layer contains ozone (O₃), which absorbs ultraviolet (UV) rays from the Sun and protects us from their harmful effects. That is why it is called the ‘Earth’s umbrella.’ Nowadays, this umbrella is depleting, creating an ‘ozone hole.’ The mechanism of ozone depletion is as follows:
1. Naturally, N₂ and O₂ in the air combine via solar radiation to produce N₂O, which depletes the ozone layer through a photochemical process.
2. However, the main reason is human activity, where CFCs released into the air reach the stratosphere unchanged. CFCs are extremely stable. UV rays from the Sun break down CFCs through free-radical reactions, which then break the ozone layer.
1. Naturally, N₂ and O₂ in the air combine via solar radiation to produce N₂O, which depletes the ozone layer through a photochemical process.
2. However, the main reason is human activity, where CFCs released into the air reach the stratosphere unchanged. CFCs are extremely stable. UV rays from the Sun break down CFCs through free-radical reactions, which then break the ozone layer.
a. CFC → Cl•
b. Cl• + O₃ → ClO• + O₂ এবং O₂ → 2O•
c. ClO• + O• → Cl• + O₂
d. ClO• + O₃ → ClO₂ + O₂
These reactions continue in a chain. As a result, a single chlorine free radical destroys thousands of ozone molecules, creating holes in the ozone layer.b. Cl• + O₃ → ClO• + O₂ এবং O₂ → 2O•
c. ClO• + O• → Cl• + O₂
d. ClO• + O₃ → ClO₂ + O₂
Question: Explain the harmful effects of ozone layer depletion.
Answer: Effect on humans: If UV rays reach the Earth directly, it will cause skin cancer, cataracts, weakened immune systems, respiratory inflammation, bronchitis, and various lung diseases.
Effect on plants and animals: UV rays hinder photosynthesis, reducing food production in plants. It reduces the production of phytoplankton, which in turn reduces the population of fish and other organisms that depend on them.
Effect on climate: The Earth’s temperature will rise, melting polar ice will increase, and sea levels will rise, submerging low-lying areas.
Effect on plants and animals: UV rays hinder photosynthesis, reducing food production in plants. It reduces the production of phytoplankton, which in turn reduces the population of fish and other organisms that depend on them.
Effect on climate: The Earth’s temperature will rise, melting polar ice will increase, and sea levels will rise, submerging low-lying areas.
Question: Describe the necessary measures to prevent ozone layer depletion.
Answer: To prevent ozone depletion, the ‘Montreal Protocol’ international treaty was signed in 1987. According to this treaty:
(i) Stop the production of CFCs and Halons by 1995;
(ii) Phase out CCl₄, CH₃Br, and Methyl chloroform;
(iii) Use hydrocarbons like Isobutane (CH₃)₃CH in CFC aerosols;
(iv) Use Hydro-chlorofluorocarbons (HCFCs) like CHF₂Cl in refrigerators;
(v) Phase out HCFCs and switch to Hydrofluorocarbons (HFCs) by 2040.
(i) Stop the production of CFCs and Halons by 1995;
(ii) Phase out CCl₄, CH₃Br, and Methyl chloroform;
(iii) Use hydrocarbons like Isobutane (CH₃)₃CH in CFC aerosols;
(iv) Use Hydro-chlorofluorocarbons (HCFCs) like CHF₂Cl in refrigerators;
(v) Phase out HCFCs and switch to Hydrofluorocarbons (HFCs) by 2040.
Question: How does the ozone layer protect us from UV rays?
Answer: Harmful UV rays are emitted along with solar radiation. The O₃ layer absorbs these UV rays. If UV rays enter the Earth, they can cause skin cancer and weaken the human immune system. Therefore, the O₃ layer protects us by absorbing these harmful UV rays.
Question: What is a Greenhouse Gas?
Answer: Gases that absorb IR radiation reflected from the Earth’s surface and increase temperature are called greenhouse gases.
Question: Explain why the Earth’s surface gets heated.
Answer: The Earth’s surface is heated by visible light, but it radiates long-wavelength infrared (IR) rays. IR rays cannot penetrate glass. CO₂ and water vapor (H₂O) are polar molecules that absorb IR radiation and increase the temperature. Heat absorbed by CO₂ and water vapor is radiated back to the Earth’s surface, further increasing the temperature. N₂, H₂, and O₂ have no greenhouse effect.
Question: Why is CO called a silent killer?
Answer: CO (Carbon Monoxide) is a silent killer because it is a colorless, odorless, and tasteless toxic gas. Humans cannot detect its presence. CO acts as an active ligand and forms a complex compound with iron in the blood’s hemoglobin, blocking oxygen flow in the body.
O₂ + Hb → O₂Hb (Oxyhemoglobin)
O₂Hb + CO → COHb (Carboxyhemoglobin) + O₂
Fe + 5CO → Fe(CO)₅ (Iron pentacarbonyl)
O₂Hb + CO → COHb (Carboxyhemoglobin) + O₂
Fe + 5CO → Fe(CO)₅ (Iron pentacarbonyl)
Question: Explain the role of greenhouse gases in global warming.
Answer: Gases like CO₂, CH₄, N₂O, and CFC create the greenhouse effect. The Earth’s surface radiates long-wavelength infrared (IR) rays which are absorbed by these atmospheric gases. This heat is radiated back to the Earth’s surface, increasing the global temperature.
Question: Why is CO₂ called a greenhouse gas?
Answer: CO₂ retains more heat than other gases and stays near the Earth’s surface due to its weight. Its concentration is increasing daily, causing the Earth’s temperature to rise. This event is known as the greenhouse effect, hence it is called a greenhouse gas.
Question: Explain how CFC helps in increasing environmental temperature.
Answer: CFCs produce chlorine free radicals that destroy the ozone layer. Through the holes created in the ozone layer, UV rays from the Sun enter the Earth’s atmosphere without obstruction, causing the Earth’s surface temperature to rise. Therefore, CFCs assist in increasing the environmental temperature.
Question: Write the effects of CO₂ and SO₂ pollution on the environment.
Answer: CO₂ retains a significant portion of reflected heat, preventing it from escaping into space, thus increasing atmospheric temperature. CO₂ and SO₂ react with oxygen and water in the air to produce carbonic acid, sulfurous acid, and sulfuric acid, which cause acid rain. This kills fish in water bodies, prevents crop growth in soil, and causes significant damage to buildings and structures.
A. Knowledge-based Questions and Answers (Marks – 1)
1. What is the Ozone Layer?
Answer: The layer of air containing ozone gas, located at an altitude of 15-30 km (or 20-50 km according to some sources) within the stratosphere or the calm layer, is called the ozone sphere or ozone layer.
2. What is an Ozone Hole?
Answer: The depletion of the ozone layer located in the stratosphere, at an altitude of 20-30 km from the Earth’s surface, creates a hole known as an “ozone hole.” Scientist Farman identified the depletion of the ozone layer as an ozone hole.
3. What is a Greenhouse Gas?
Answer: Gases that absorb infrared (IR) radiation reflected from the Earth’s surface and increase its temperature are called greenhouse gases.
4. What is CFC?
Answer: The fluorine and chlorine derivatives of methane and ethane are called CFCs.
5. What is the commercial name of CFC gas?
Answer: The commercial name of CFC gas is Freon.
B. Analytical Questions and Answers (Marks – 2)
Question: Explain the mechanism of ozone layer depletion.
Answer: CFCs reach the stratosphere unchanged due to their high stability. UV rays trigger a photolysis process, producing chlorine free radicals. These radicals react with ozone (O₃), breaking it down.
a. CFC → Cl•
b. Cl• + O₃ → ClO• + O₂ and O₂ → 2O•
c. ClO• + O• → Cl• + O₂
d. ClO• + O₃ → ClO₂ + O₂
These reactions form a chain. A single chlorine free radical destroys thousands of ozone molecules, creating holes in the ozone layer.b. Cl• + O₃ → ClO• + O₂ and O₂ → 2O•
c. ClO• + O• → Cl• + O₂
d. ClO• + O₃ → ClO₂ + O₂
Question: Explain the harmful effects of ozone layer depletion.
Effect on humans: Direct exposure to UV rays causes skin cancer, cataracts, and immune system suppression, alongside respiratory issues like bronchitis.
Effect on plants and animals: UV rays inhibit photosynthesis, reducing crop yields. It also reduces phytoplankton production, which harms fish and other aquatic populations.
Effect on climate: Global temperatures rise, polar ice melts, and sea levels increase, submerging low-lying regions.
Effect on plants and animals: UV rays inhibit photosynthesis, reducing crop yields. It also reduces phytoplankton production, which harms fish and other aquatic populations.
Effect on climate: Global temperatures rise, polar ice melts, and sea levels increase, submerging low-lying regions.
Question: Describe the necessary measures to prevent ozone layer depletion.
Answer: The ‘Montreal Protocol’ was signed in 1987 to prevent ozone depletion. The measures include:
(i) Stopping the production of CFCs and Halons by 1995; (ii) Phasing out CCl₄, CH₃Br, and Methyl chloroform; (iii) Using hydrocarbons like Isobutane in CFC aerosols; (iv) Using HCFCs in refrigerators; (v) Switching from HCFCs to HFCs by 2040.
(i) Stopping the production of CFCs and Halons by 1995; (ii) Phasing out CCl₄, CH₃Br, and Methyl chloroform; (iii) Using hydrocarbons like Isobutane in CFC aerosols; (iv) Using HCFCs in refrigerators; (v) Switching from HCFCs to HFCs by 2040.
Question: How does the ozone layer protect us from UV rays? Explain.
Answer: Harmful UV rays from the Sun are absorbed by the O₃ layer. If these rays reached the Earth, they would cause skin cancer and weaken our immune system. Thus, the O₃ layer protects us by absorbing these harmful radiations.
Question: Explain why the Earth’s surface gets heated.
Answer: The Earth is heated by visible light, which then radiates long-wavelength infrared (IR) rays. IR rays cannot penetrate glass. CO₂ and water vapor (H₂O) are polar molecules; they absorb these IR rays and increase the temperature. The heat is radiated back to the Earth’s surface. N₂, H₂, and O₂ do not contribute to this greenhouse effect.
Question: Why is CO called a silent killer? Explain.
Answer: CO is a colorless, odorless, and tasteless toxic gas. Humans cannot detect it. CO acts as an active ligand and binds with the iron in hemoglobin, which is stronger than oxygen’s bond. This forms Carboxyhemoglobin, blocking oxygen flow in the blood.
O₂ + Hb → O₂Hb (Oxyhemoglobin)
O₂Hb + CO → COHb (Carboxyhemoglobin) + O₂
Fe + 5CO → Fe(CO)₅
O₂Hb + CO → COHb (Carboxyhemoglobin) + O₂
Fe + 5CO → Fe(CO)₅
Question: Explain the role of greenhouse gases in global warming.
Answer: Gases like CO₂, CH₄, N₂O, and CFC create the greenhouse effect. Visible light penetrates the greenhouse, but the surface radiates IR rays which are trapped by these gases. The trapped heat is radiated back to the surface, causing global temperatures to rise.
Question: Why is CO₂ called a greenhouse gas?
Answer: CO₂ is emitted from various sources and is increasing daily. Being heavy, it stays near the surface. CO₂ retains more heat than other gases, causing the Earth’s temperature to rise. This effect is known as the greenhouse effect, hence it is called a greenhouse gas.
Question: Explain how CFC helps in increasing environmental temperature.
Answer: CFCs release chlorine free radicals that destroy the ozone layer. The resulting hole allows UV rays to enter the atmosphere unchecked, which increases the Earth’s surface temperature. Therefore, CFCs contribute to the rise in environmental temperature.
Question: Write the effects of CO₂ and SO₂ pollution on the environment.
Answer: CO₂ increases atmospheric temperature by trapping heat. Both CO₂ and SO₂ react with atmospheric oxygen and water to form carbonic, sulfurous, and sulfuric acids, leading to acid rain. This kills fish, damages crops, and degrades infrastructure.
C. Multiple Choice Questions (MCQ) and Answers
1. Which gas has the most significant role in creating the greenhouse effect?
Answer: (c) CO₂
2. What is the current concentration of methane (CH₄) gas in the atmosphere?
Answer: (b) 1.7 ppm
3. How many times higher is the heat-trapping capacity of tropospheric ozone compared to CO₂?
Answer: (b) 10 times
4. What is the average annual growth rate of CFC gases?
Answer: (c) 3-4%
5. Due to the greenhouse effect, by how many degrees could the Earth’s temperature rise by 2050?
Answer: (d) 6°C
6. As a result of ice melting, by how many centimeters could the sea level rise by 2087?
Answer: (b) 50-100 cm
7. How many billion people could become homeless due to climate change caused by the greenhouse effect?
Answer: (b) 1 billion
8. A rise of how many feet in sea level would turn the southern region of Dhaka and the haor-baor areas of Sylhet into the sea?
Answer: (c) 9 feet
9. Due to the greenhouse effect, how many upazilas (thanas) in Bangladesh will be severely affected?
Answer: (b) 62
10. Up to which districts could the coastline of Bangladesh advance due to rising sea levels?
Answer: (b) Jessore, Faridpur, Chandpur
11. Due to the greenhouse effect, the population of how many Royal Bengal Tigers in the Sundarbans could be severely impacted?
Answer: (b) Approx. 350
12. In which country has summer lengthened due to the greenhouse effect, with rainfall occurring from October to March?
Answer: (a) Australia
13. What is the average duration of a drought in Bangladesh?
Answer: (b) 15-100 days
14. Which cold countries are at risk of turning into desert regions due to the greenhouse effect?
Answer: (a) Russia and Canada
15. Which of the following is an “adaptation strategy” to reduce the greenhouse effect?
Answer: (b) Phasing out auto-rickshaws and auto-tempos
16. What is the average duration of a cyclone in Bangladesh?
Answer: (c) 1-24 hours
17. How many times higher is the heat-trapping capacity of Nitrous Oxide (N₂O) compared to CO₂?
Answer: (c) 200 times
18. What wavelength of harmful rays does the ozone layer absorb from solar radiation?
Answer: (b) 800-2300 nm
19. How many square kilometers of land in Bangladesh could be submerged due to the greenhouse effect?
Answer: (b) 22,000 sq km
20. To protect environmental balance in brick kilns, the use of what has been recommended instead of wood?
Answer: (b) Natural gas
